PokéBase - Pokémon Q&A
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I have tried to use the proteins and HP up and the other ones on camerupt and it comes up saying it won't have any effect on it,

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That message will usually come up if your Pokémon already have max EV’s. That means it already has 510 EV’s.

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Your Pokémon already has max EVs.

In all core series games since Generation III, vitamins that affect stats increase a Pokémon's EVs for a given stat by 10 EV points, but can't increase the total EVs beyond a maximum of 510.

Since your Pokémon already has 510 EV points, it can't get any more EVs, unless if you decrease the EVs using an EV-reducing Berry, and then increase the EVs with the stat you choose.

Source (Vitamins)

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